Temperature-depended wettability of conductive films based on electrophoretic silver nanoparticle concentrates

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The Doctor Blade method was employed to obtain homogeneous, rough films comprising concentrated organosols of silver nanoparticles stabilised with bis-(2-ethylhexyl)sodium sulphosuccinate. The films exhibited a precious metal content of up to 73 at. %. The study provides a comprehensive account of the alterations in the film wetting capacity in response to the thermal treatment conditions, spanning a range of temperatures from 50 to 500°C. The evolution of the film wettability is not a linear process due to the nanoparticle sintering and thermal decomposition of stabiliser molecules. Experimental evidence indicated that the transition from non-conductive to conductive coatings (from 500 to 105 mOhm/□) was accompanied by a notable increase in the contact angle (from 25 to 78°).

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Sobre autores

S. Babashova

Институт неорганической химии им. А.В. Николаева СО РАН

Email: kolodin@niic.nsc.ru
Rússia, Новосибирск

V. Bocharov

Институт неорганической химии им. А.В. Николаева СО РАН

Email: kolodin@niic.nsc.ru
Rússia, Новосибирск

V. Sulyaeva

Институт неорганической химии им. А.В. Николаева СО РАН

Email: kolodin@niic.nsc.ru
Rússia, Новосибирск

E. Maksimovskiy

Институт неорганической химии им. А.В. Николаева СО РАН

Email: kolodin@niic.nsc.ru
Rússia, Новосибирск

A. Kolodin

Институт неорганической химии им. А.В. Николаева СО РАН

Autor responsável pela correspondência
Email: kolodin@niic.nsc.ru
Rússia, Новосибирск

A. Bulavchenko

Институт неорганической химии им. А.В. Николаева СО РАН

Email: kolodin@niic.nsc.ru
Rússia, Новосибирск

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2. Fig. 1. Dependence of the contact angle of water on silver films on the calcination temperature (a), as well as optical microscopy images in direct (b) and reverse light (c) modes of silver films without calcination (background systems) and calcined at T = 150, 200 and 250°C.

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3. Fig. 2. AFM 3D scans and roughness profiles of the substrate (a) and silver films (without calcination (b) and calcined at a temperature of 150 (c), 200 (d), 250 (e), 300 (e), 350 (g), 400 (h), 450 (i), 500°C (j)). The dotted lines on the scans indicate the areas where the profiles were recorded.

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4. Fig. 3. Change in the arithmetic mean roughness (a), root-mean-square roughness (b), excess (c) and asymmetry (d) of the roughness profile of silver films with variation in the calcination temperature. The substrate data are marked with a black marker.

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5. Fig. 4. Changes in the values ​​of depth (a) and diameter of the pore inlet (b), as well as porosity (c) and density (d) of silver films (after calcination at a temperature of 150–500°C).

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6. Fig. 5. Characteristics of the organosol of silver nanoparticles: data from transmission electron microscopy (a), photon correlation spectroscopy (b) and the method of phase analysis of scattered light (c).

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7. Fig. 6. Comparison of roughness and wettability data (a), as well as elemental composition and wettability (b) of silver films calcined at a temperature of 300–500°C. The dotted lines indicate the correlation dependences (Rq = 0.0303cosθ – 0.0134, R2 = 0.8919 and C(O) = 20.61 cosθ + 3.3661, R2 = 0.9950).

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8. Fig. 7. Results of current spectroscopy (2D AFM scan and voltammogram in the inset) of the surface of silver films before (a) and after (b) calcination at a temperature of 250°C. The location of the voltammogram recording is indicated by a dot on the scan.

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9. Fig. 8. Dependence of surface resistance on the annealing temperature of the silver film.

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