Physicochemical properties of disperse-filled ethylene-octene copolymer

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Resumo

The article is aimed at developing innovations in the field of hybrid polymer nanomaterials and investigating their structural, thermodynamic, and physico-mechanical properties. Filling the ethylene-octene copolymer with Ni nanoparticles as well as basalt scales increases the elasticity of the composite by a 25% and also causes an increase in strength by a 15%. Obtained results open possibility to evaluate influence of chemical nature, sizes and content of different kinds of fillers for improvement thermostability and elasticity of the new hybrid polymer nanomaterials.

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Sobre autores

V. Myasoedova

Federal Research Center of Chemical Physics named after N.N. Semenov, Russian Academy of Sciences

Autor responsável pela correspondência
Email: veravm777@gmail.com
Rússia, Moscow

D. Golobokov

University of Science and Technology “MISIS”

Email: veravm777@gmail.com
Rússia, Moscow

Bibliografia

  1. Trakhtenberg L.I., Ikim M.I., Ilegbusi O.J. et al. // Chemosensors. 2023. V. 11. № 6. P. 320. https://doi.org/10.3390/ chemosensors11060320
  2. Kozhushner M.A., Trakhtenberg L.I., Bodneva V.L. et al. // J. Phys. Chem. C. 2014. V. 118. № 21. P. 11440. https://doi.org/10.1021/jp501989k
  3. Trakhtenberg L.I., Gerasimov G.N., Grigor’ev E.I. // Russ. J. Phys. Chem. A. 1999. V. 73. P. 209.
  4. Zhukov A.M., Solodilov V.I., Tretyakov I.V. et al. // Russ. J. Phys. Chem. B. 2022. V. 16. P. 926. https://doi.org/10.1134/S199079312205013X
  5. Guymon G.G., Malakooti M.H. // J. Polym. Sci. 2022. V. 60. № 8. P. 1300. https://doi.org/10.1002/pol.20210867
  6. Nesmelov A.A., Zavyalov S.A., Malakhov S.N. et al. // Russ. J. Phys. Chem. B. 2023. V. 17. № 4. P. 826.
  7. Trzepieci’nski T., Najm S.M., Sbayti M. et al. // J. Compos. Sci. 2021. V. 5. № 8. P. 217. https://doi.org/10.3390/jcs5080217
  8. Tran V.V., Nu T.T.V., Jung H.-R. et al. // Polymers. 2021. V. 13. № 18. P. 3031. https://doi.org/10.3390/polym13183031
  9. Aloev V.Z., Zhirikova Z.M., Tarchokova M.A. // ChemChemTech. 2020. V. 63. P. 81. https://doi.org/10.6060/ivkkt.20206304.6158
  10. Li Z., Wu W., Chen H. et al. // Roy. Soc. Chem. Adv. 2013. V. 3. P. 6417. https://doi.org/10.1039/c3ra22482a
  11. Lebedeva E.A., Astafieva S.A., Trukhinov D.K. et al. // Russ. J. Phys. Chem. B. 2023. V. 17. P. 191. https://doi.org/10.1134/S1990793123010244
  12. Myasoedova V., Zakharova E., Vasiljev I. // Annals DAAAM Proc. Intern. DAAAM Sympos. 2021. V. 32. P. 177. https://doi.org/10.2507/32nd.daaam.proceedings.027

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2. Fig. 1. SEM micrographs of synthesized Ni nanoparticle powder samples with different resolutions.

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3. Fig. 2. Histogram of the size distribution of Ni nanoparticles.

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4. Fig. 3. X-ray phase study data for Ni nanoparticles.

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5. Fig. 4. Photos of Ni/NiO/SEO composite extrudate samples in the form of strands.

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6. Fig. 5. Photos of BC composite extrudate samples in the form of strands.

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7. Fig. 6. Nomograms obtained from the experimental data: maximum strength (a) and relative elongation (b) of composites based on EOS filled with basalt scales with the following sizes: 0–50 μm (1), 50–100 μm (2), 100–160 μm (3), 0–300 μm (4).

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8. Fig. 7. Simultaneous TG/DSC analysis of EOS in the temperature range of 20–350 °C.

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9. Fig. 8. Simultaneous TG/DSC analysis of the 0.5 wt. % Ni/EOS composite in the temperature range of 20–350 °C.

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10. Fig. 9. TGA curves for the following composites: 10 wt. % BC/EOS (1), EOS (2), 2.5 wt. % BC/EOS (3), 5 wt. % BC/EOS (4).

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11. Fig. 10. DSC curves for the same composite compositions as in Fig. 9.

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Declaração de direitos autorais © Russian Academy of Sciences, 2024